Contributions to the mixed-alkali effect in molecular dynamics simulations of alkali silicate glasses
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چکیده
منابع مشابه
Optical and Thermal Properties of Mixed Alkali Phosphate Based Glasses
Glassy samples with a composition of 40P2O5–30V2O5–(30-x)Li2O– xK2O, 0<x<30 (mol %) were prepared by the conventional melt quenching technique in two forms of bulk and blown film. X-ray diffraction patterns corroborated the amorphous feature of the samples. Density of samples was investigated by using Archimedes principle. Based on absorption and reflection spectra, indirect a...
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Introducing an interaction parameter γ, we implement modifier interaction and the mixed-alkali effect into bond constraint theory and apply this extension for simplistic property prediction on ternary phosphate glasses. The severity of the mixed-alkali effect results from the interplay of two simultaneous contributions: bond constraints on the modifier species soften and stiffen with decreasing...
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The thermal and dielectric anomalies of window-type glasses at low temperatures (T < 1 K) are rather successfully explained by the two-level systems (2LS) standard tunneling model (STM). However, the magnetic effects discovered in the multisilicate glasses in recent times, magnetic effects in the organic glasses, and also some older data from mixed (SiO₂)(1-x) (K₂O)(x) and (SiO₂)(1-x) (Na₂O)(x)...
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The physical properties of fluid alkali metals and mercury have been studied intensively both theoretically [1] and experimentally [2, 3, 4]. The most interesting feature in fluid metals compared with LennardJones systems is the density dependence of the interaction between the particles. This leads to a strong state dependence of the thermodynamic properties and to a metal-to-nonmetal transiti...
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Lead free, eco-friendly bismuth borate glasses doped with alkali oxides of composition xLi2O+(30-x)Na2O+55B2O3+15Bi2O3 (x = 5,10,15,20,25) were prepared by melt quenching technique. Amorphous nature of glasses was confirmed by X-ray diffraction. Density measurements were carried out at room temperature by standard principle of Archimedes with Xylene as an immersion liquid. The non-linear ...
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ژورنال
عنوان ژورنال: Physical Review B
سال: 2005
ISSN: 1098-0121,1550-235X
DOI: 10.1103/physrevb.72.214202